************************************************************* ADVANCED REMEDIATION MIXING, INC. (formerly Chemfix Technologies/CeTech Resources) (Solidification and Stabilization) This vendor is participating in the EPA Superfund Innovative Technology Evaluation (SITE) Program. The following technology profile has been reproduced from the SITE Technology Profile document, 7th edition. The SITE profile has been supplemented by MVA Consulting Inc. using information obtained from the vendor or from other SITE publications referenced at the end of this file. ************************************************************* TECHNOLOGY DESCRIPTION: In this solidification and stabilization process, pozzolanic materials react with polyvalent metal ions and other waste components to produce a chemically and physically stable solid material. Optional accelerators and precipitators may include soluble silicates, carbonates, phosphates, and borates. The end product may be similar to a clay-like soil, depending upon the characteristics of the raw waste and the properties desired in the end product. Typically, the waste is first blended in a reaction vessel with pozzolanic materials that contain calcium hydroxide. This blend is then dispersed throughout an aqueous phase. The reagents react with one another and with toxic metal ions, forming both anionic and cationic metal comple-xes. Pozzolanic accelerators and metal precipi-tating agents can be added before or after the dry binder is initially mixed with the waste. When a water soluble silicate reacts with the waste and the pozzolanic binder system, colloi-dal silicate gel strengths are increased within the binder-waste matrix helping polyvalent metal cations. A large percentage of the heavy metals become part of the calcium silicate and aluminate colloidal structures formed by the pozzolans and calcium hydroxide. Some of the metals, such as lead, adsorb to the surface of the pozzolanic structures. The entire pozzolanic matrix, when physically cured, decreases toxic metal mobility by reducing the incursion of leaching liquids into and out of the stabilized matrices. With modifications, the system (shown below) may be applied to wastes containing between 10 to 100 percent solids. WASTE APPLICABILITY: This process is suitable for contaminated soils, sludges, ashes, and other solid wastes. The process is particularly applicable to electroplating sludges, electric arc furnace dust, heavy metal contaminated soils, oil field drilling muds and cuttings, municipal sewage sludges, and residuals from other treatment processes. This process effectively treats heavy metals, such as antimony, arsenic, lead, cadmium, hexavalent chromium, mercury, copper, and zinc. In addition, when combined with specialized binders and additives, this process can stabilize low-level nuclear wastes. STATUS: The solidification and stabilization process was demonstrated in March 1989 at the Portable Equipment Salvage Company site in Clackamas, Oregon. The Technology Evaluation Report was published in September 1990 (EPA/540/5-89/011a). The Applications Analysis Report was completed in May 1991 (EPA/540/A5-89/011). [The objective of this demonstration was to solidify metals, although PCBs were present in the untreated material at concentrations up to 1,900 ppm. PCBs did not leach from the soldified mass after treatment, but these results are inconclusive since PCBs did not leach from the untreated material.] In addition, several full-scale remediation projects have been completed since 1977, inclu-ding a high solids CHEMSET reagent protocol designed to treat 30,000 cubic yards of hexavalent chromium-contaminated, high solids waste. The average chromium level after treatment was less than 0.15 milligram per liter and met toxicity characteristic leaching procedure (TCLP) criteria. The final product permeability was less than 1 10-4 centimeters per second (cm/sec). DEMONSTRATION RESULTS: The demonstration yielded the following results: > The technology effectively reduced copper and lead concentrations in the wastes. The concentrations in the TCLPextracts from the treated wastes were 94 to 99 percent less than those from the untreated wastes. Total lead concen-trations in the untreated waste approached 14 percent. > The volume of excavated waste material increased between 20 to 50 percent after treatment. > During the durability tests, the treated wastes showed little or no weight loss after 12 cycles of wetting and drying or freezing and thawing. > The unconfined compressive strength of the wastes varied between 27 and 307 pounds per square inch after 28 days. Hydraulic conductivity of the treated material ranged between 1 10-6 cm/sec and 6.4 10-7 cm/sec. > Air monitoring data suggest there was no significant volatilization of polychlorinated biphenyls during the treat- ment process. > Treatment costs were approximately $73 per ton, including mobilization, labor, reagents, and demobilization, but not disposal. FOR FURTHER INFORMATION: EPA PROJECT MANAGER: Edwin Barth U.S. EPA Center for Environmental Research Information 26 West Martin Luther King Drive Cincinnati, OH 45268 513-569-7669 Fax: 513-569-7585 TECHNOLOGY DEVELOPER CONTACT: Sam Pizzitola Advanced Remediation Mixing, Inc. 711 Oxley Street Kenner, LA 70062 504-461-0466 Fax: 504-466-9032 __________________________________________________________ Sources of information in this profile: EPA Superfund Innovative Technology Evaluation Program Technology Profiles Seventh Edition, November 1994. EPA/540/R-94/526. ***********************************************************