************************************************************* EVALUATION AND SELECTION OF TECHNOLOGIES This file will explain the EPA procedure for evaluating remedial alternatives at Superfund sites, and will evaluate each major PCB treatment option in a general way. It is only partially implemented at this time, but we expect to complete it this summer. Contents Implemented Feasibility Study Criteria Defined.............. yes Generic FS Evaluations for Technology Types Thermal Desorption......................... Solvent Extraction......................... Vitrification.............................. yes Solidification............................. Soil Washing............................... NYSDEC Scoring Procedure........................ ************************************************************* FEASIBILITY STUDY CRITERIA The nine criteria defined in the EPA Remedial Investigation / Feasibility Study guidance document are typically used to assess the merits of each alternative individually, then relative to the other alternatives. The nine criteria are summarized below. 1. OVERALL PROTECTION OF HUMAN HEALTH AND THE ENVIRONMENT Assess whether or not a remedy provides adequate protection and describes how risks posed through each pathway are eliminated, reduced or controlled through treatment, engineering controls, or institutional controls. 2. COMPLIANCE WITH ARARS Addresses whether an alternative meets the requirements of applicable or relevant environmental statutes and guidelines. 3. LONG-TERM EFFECTIVENESS AND PERMANENCE Refers to the ability of a remedy to maintain reliable protection of human health and the environment once cleanup goals have been met. 4. REDUCTION OF TOXICITY, MOBILITY AND VOLUME THROUGH TREATMENT considers whether the alternative employs waste treatment, the amount of material treated or destroyed, the degree of expected reductions in toxicity, mobility and volume, the degree to which treatment is irreversible, and the type and quantity of residual waste remaining. 5. SHORT TERM EFFECTIVENESS Considers the risk to the community and the environment during implementation of the remedy, and the time required to achieve protection. 6. IMPLEMENTABILITY Technical and administrative feasibility of the remedy, including the availability of services and materials needed to implement a particular option. 7. COST Includes estimated capital, operation and maintenance cost, and net present worth cost. 8. AGENCY ACCEPTANCE Addresses technical and administrative issues and concerns the support agencies may have regarding each alternative. 9. COMMUNITY ACCEPTANCE Addresses the issues and concerns the public may have to each of the alternatives. Source: MVA Consulting, Inc. ***************************************************************** GENERIC FS EVALUATIONS OF PCB TREATMENT OPTIONS IN-SITU VITRIFICATION 1. OVERALL PROTECTION OF HUMAN HEALTH AND THE ENVIRONMENT Provides both short term and long term effectiveness by destroying organic contaminants and immobilizing inorganic material. Remediation can be performed in-situ, reducing the need for excavation. Requires off-gas treatment systems to control airborne emissions. System can be specifically designed to handle emissions generated by he contaminants in the media being treated. Technology can simultaneously treat a mixture of waste types. 2. COMPLIANCE WITH ARARS Requires compliance with RCRA treatment, storage and land disposal regulations (for a hazardous waste). Successfully treated solid waste may be de-listed or handled as non-hazardous waste. Operation of on-site treatment unit may require compliance with location-specific ARARs. Emissions controls may be needed to ensure compliance with air quality standards depending on local ARARs and test soil components. Scrubber water will likely require secondary treatment before discharge to POTW or surface water bodies. Disposal requires compliance with Clean Water Act regulations. 3. LONG TERM EFFECTIVENESS Effectively destroys organic contamination and immobilizes inorganic material. Reduces the likelihood of contaminants leaching from treated soil. In-situ vitrification (ISV)glass is thought to have a stability similar to volcanic obsidian. The vitrified product is conservatively estimated to remain chemically and physically stable for approximately 1,000,000 years. May allow re-use of property after remediation. 4. SHORT TERM EFFECTIVENESS Effectively destroys organic contamination and immobilizes inorganic material. Vitrification of a single 15-foot deep treatment cell may be accomplished in approximately ten days. Treatment times will vary with actual treatment depth and site- specific conditions. Presents potential short-term exposure risk to workers operating process equipment. Temperature and electric hazards exist. Some short-term risks associated with air emissions are dependent upon test material composition and off-gas treatment system design. Staging, if required, involves excavation and construction of treatment areas. A potential for fugitive emissions and exposure exists during excavation and construction. 5. REDUCTION OF TOXICITY, MOBILITY OR VOLUME THROUGH TREATMENT Significantly reduces toxicity and mobility of waste through treatment. Volume reductions of 20 to 50 percent are typical after treatment. Some inorganic contaminants, especially volatile metals, may escape the vitrification process and require subsequent treatment by the off-gas treatment system. Some treatment residues (i.e., filters, personal protective equipment) may themselves be treated during subsequent melts. Residues from the final application may require special disposal. Volume of scrubber water generated is highly dependent upon soil moisture content, ambient air humidity, and soil particulate levels in the off-gas. 6. IMPLEMENTABILITY A suitable source of electric power is required to utilize this technology. Equipment is transportable and can be brought to the site using conventional shipping methods. Weight restrictions on tractor/trailers may vary from state to state. Necessary support equipment includes earth moving equipment for staging treatment areas (if required) and covering treated areas with clean soil. A crane is required for off-gas hood placement and movement. The staging of treatment areas is recommended for areas where the contamination is limited to shallow depths (less than eight feet). The soil oxide composition must provide sufficient electrical conductivity in the molten state and adequate quantities of glass formers to produce a vitrified product. Oxides can be added to soil to correct for deficiencies. Groundwater should be diverted away from treatment areas to improve economic viability. 7. COST The estimated treatment cost when the soil is staged in nine 15-ft deep cells is approximately $430 per ton ($780 per cubic yard) based on the Parson's site demonstration. Costs are highly site specific. Treatment is most economical when treating large sites to maximum depth. Electric power is a major cost element associated with ISV. Other important factors (in order of significance) include labor costs, startup and fixed costs, equipment costs, and facility modifications and maintenance costs. Moisture content of the waste being treated directly influences the treatment cost since electric energy must be used to vaporize water before soil melting occurs. Sites that require staging and extensive site preparation will have higher overall cost. Source: EPA SITE Technology Capsule, Geosafe Corporation In Situ Vitrification Technology, November 1994 (EPA 540/R-94/520a)